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Shell may succumb to isotopic exchange if it interacts with carbon from percolating ground acids or recrystallization when shell aragonite transforms to calcite and involves the exchange of modern calcite.The surrounding environment can also influence radiocarbon ages.Compared to conventional radiocarbon techniques such as Libby's solid carbon counting, the gas counting method popular in the mid-1950s, or liquid scintillation (LS) counting, AMS permitted the dating of much smaller sized samples with even greater precision.Regardless of the particular 14C technique used, the value of this tool for archaeology has clearly been appreciated.The introduction of "old" or "artificial" carbon into the atmosphere (i.e., the "Suess Effect" and "Atom Bomb Effect", respectively) can influence the ages of dates making them appear older or younger than they actually are.

Radiocarbon dating is especially good for determining the age of sites occupied within the last 26,000 years or so (but has the potential for sites over 50,000), can be used on carbon-based materials (organic or inorganic), and can be accurate to within ±30-50 years.Probably the most important factor to consider when using radiocarbon dating is if external factors, whether through artificial contamination, animal disturbance, or human negligence, contributed to any errors in the determinations.For example, rootlet intrusion, soil type (e.g., limestone carbonates), and handling of the specimens in the field or lab (e.g., accidental introduction of tobacco ash, hair, or fibers) can all potentially affect the age of a sample.Bioturbation by crabs, rodents, and other animals can also cause samples to move between strata leading to age reversals.

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In contrast to relative dating techniques whereby artifacts were simply designated as "older" or "younger" than other cultural remains based on the presence of fossils or stratigraphic position, 14C dating provided an easy and increasingly accessible way for archaeologists to construct chronologies of human behavior and examine temporal changes through time at a finer scale than what had previously been possible.The application of Accelerator Mass Spectrometry (AMS) for radiocarbon dating in the late 1970s was also a major achievement.

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